<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Archiving and Interchange DTD v1.0 20120330//EN" "JATS-archivearticle1.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink">
  <front>
    <journal-meta />
    <article-meta>
      <title-group>
        <article-title>Putting Theory into Practice with Technology in Chemistry Education</article-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <string-name>Shaykhah S. Aldosari</string-name>
          <email>shaykhah.aldosari@plymouth.ac.uk</email>
          <xref ref-type="aff" rid="aff0">0</xref>
          <xref ref-type="aff" rid="aff1">1</xref>
        </contrib>
        <contrib contrib-type="author">
          <string-name>Davide Marocco</string-name>
          <email>davide.marocco@plymouth.ac.uk</email>
          <xref ref-type="aff" rid="aff1">1</xref>
        </contrib>
        <aff id="aff0">
          <label>0</label>
          <institution>College of Computer and Information Sciences, Princess Nourah Bint Abdulrahman Univesity</institution>
          ,
          <addr-line>Riyadh</addr-line>
          ,
          <country country="SA">Saudi Arabia</country>
        </aff>
        <aff id="aff1">
          <label>1</label>
          <institution>School of Computing, Electronic and Mathematics, Plymouth University</institution>
          ,
          <addr-line>Plymouth</addr-line>
          ,
          <country country="UK">United Kingdom</country>
        </aff>
      </contrib-group>
      <pub-date>
        <year>2015</year>
      </pub-date>
      <fpage>23</fpage>
      <lpage>28</lpage>
      <abstract>
        <p>In recent years the field of alternative haptic interface is expanding and improvements are being made by developing, testing and refining devices along with software to give users the possibility of inter- acting with three dimensional virtual objects in an intuitive way. Such technology can play a significant role in education, especially as complements of MOOCs delivery. This paper presents a description of an educational haptic system for chemistry experiment simulations and molecular visualization that can complement a virtual delivery system by providing hands-on experiences. It also describes some didactic scenarios and discusses current results and future works.</p>
      </abstract>
      <kwd-group>
        <kwd>Haptics</kwd>
        <kwd>haptic interface</kwd>
        <kwd>technology enhanced learning</kwd>
        <kwd>chemistry education</kwd>
        <kwd>e-learning</kwd>
        <kwd>simulation</kwd>
        <kwd>molecular visualization</kwd>
      </kwd-group>
    </article-meta>
  </front>
  <body>
    <sec id="sec-1">
      <title>-</title>
      <p>
        In recent years, the evolution of technology has influenced education in several
ways. Various tools and methods based on visual interaction technologies have been
introduced that help students to acquire knowledge through simulation. It has been
realized that virtual visualization could solve the difficulty in under- standing certain
aspects of the real world and help learners to fully grasp the idea behind scientific
rules and laws or other subjects rather than just having theoretical knowledge [
        <xref ref-type="bibr" rid="ref1">1</xref>
        ].
      </p>
      <p>
        There is a general consensus on two different approaches to learning. One is
passive learning, in which students are asked to sit and understand the theories through
visual and auditory cues. This way of learning can be boring for the students and
diverts their attention after some time. On the other hand, active learning is a means of
learning in which the students are directly involved. They have control over learning,
they explore a concept, and they expand their energies to make decisions. This
method of learning is recognized to develop the interest of the students and motivates them
to explore and learn more [
        <xref ref-type="bibr" rid="ref2">2</xref>
        ].
      </p>
      <p>
        A recent research has found that the use of acoustic and visual presentation
techniques works exceptionally well in educational domains. In 1996, [
        <xref ref-type="bibr" rid="ref3">3</xref>
        ] shows that
displays for educational purposes are primarily vision based even in the field of virtual
reality and up until now, the elected methodology in education is based on a passive
approach of learning. More recently, newer methods of teaching delivery exists, such
as MOOCs and online virtual labs, which allows thousands of students to access
lectures and lessons from everywhere in the world. However, a perceived missing
element of such methodology is the fact that students have difficulties in actively engage
in the training, as often there is no means for the students to actually be active in the
learning process. Indeed, many available MOOCs today are based on lectures and
visual contents [
        <xref ref-type="bibr" rid="ref4">4</xref>
        ]. For example, imagine a task assigned to a student, in which the
student will learn a method to replace a devices component. Without getting the real
touch and feel of that object under simulation, this task can be meaningless.
      </p>
      <p>
        In contrast, teaching practices based on haptic technologies within an overall
MOOC ecosystem can encourage active participation of students and can provide a
better understanding by means of direct interactions with the course material as it
exists in the real world [
        <xref ref-type="bibr" rid="ref5">5</xref>
        ]. Haptic technologies and modern visualization systems can
provide active elements in the training process that may greatly help to complement
the current delivery methodology.
      </p>
      <p>
        Haptic technology is already applied in various fields, like surgical simulation,
medical training and scientific visualization [
        <xref ref-type="bibr" rid="ref6">6</xref>
        ]. The use of haptic technology in
education has been a revolution to the learning experience. The learning experience that
is gained through the use of haptic technology produces interesting results and
motivates students [
        <xref ref-type="bibr" rid="ref7">7</xref>
        ]. Moreover, haptic technology has come up with a great value
addition for students with visual impairment [
        <xref ref-type="bibr" rid="ref7">7</xref>
        ].
      </p>
      <p>
        Within this field, haptic-based chemistry systems are regarded as a new topic and
most of the current interactive tools and systems based on haptic feedback are
suggested to be used by postgraduate chemistry studies and professionals. In addition,
they are not combined with molecule virtualization system and virtual labs. Therefore,
the research on using haptic devices in education, specifically in the chemistry field,
is becoming very important. An overview of examples of haptic based labs and
visualization systems in chemistry education and their evaluations is provided in [
        <xref ref-type="bibr" rid="ref8">8</xref>
        ].
      </p>
      <p>Based on our research in using haptic technology in education, we developed a
prototype of a haptic system that combines the possibility of replicate chemistry
experiments in simulation with 3D molecular visualization. This sys- tem could be
applied both in research and e-learning.
2</p>
    </sec>
    <sec id="sec-2">
      <title>Materials and methods</title>
      <p>We are developing an educational haptic system for chemistry experiment
simulations and molecular visualization. The system uses an easily available haptic device,
which is the Leap Motion controller, with 3D graphical user interface.</p>
      <p>
        The potential of the Leap Motion controller is huge and it is expected to be used in
education and simulation environments to simplify learning issues. The Leap Motion
controller can recognize the position and the rotation for left and right hand models
with ten fingers composed of bone-segments. The Leap Motion was designed to
perform tasks such as exploring 3D objects with high accuracy using gestures which
makes it possible to be used for interacting with the operating system. These features
can be used to design many useful education applications [
        <xref ref-type="bibr" rid="ref9">9</xref>
        ].
      </p>
      <p>
        The Leap Motion may help students in their learning process. By virtually touching
and exploring objects, students can deal with the conceptual barriers in chemistry
science. The use of haptic technology in education actively involves and engages
students by having an interaction with the courses material such as beakers, flasks and
chemical compounds. This interaction makes them understand better and enhances
their ability to learn and grasp the concept, thus making the use of haptic technology
beneficial for students in education [
        <xref ref-type="bibr" rid="ref10">10</xref>
        ].
      </p>
      <p>The basic barrier and obstacle that students may face in the study of chemistry is
connecting between what they can see in a lab (macroscopic level) and what they
cannot directly see (microscopic level). The system described in this paper combines
the two contrasting views which are the macroscopic view at a chemical lab and the
microscopic view at a molecular level.</p>
      <p>
        The scenario-based learning methods provide users with a feeling that they are in a
chemistry lab. As a result, users can use their fingers and hands to move and rotate
objects and apply experiments scenarios similar to what is done in a real lab. In
addition, this system visualizes the characteristics of atoms, molecules, electrons and the
forces produced by the chemical bonds, which will translate into physico-chemical
terms. It can help users to form and create complex molecular structures in virtual
reality and understand the binding affinity of macromolecular interactions [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ].
3
      </p>
    </sec>
    <sec id="sec-3">
      <title>Preliminary Result</title>
      <p>A student using the haptic device system with its PC is shown in Fig. 1. Our
system introduces two chemical experiments that can be used in chemistry with
secondary school students, who can have benefit by practicing the experiments techniques
and steps in a virtual lab environment before applying them in a real lab. The students
can also benefit from the system to understand the chemical changes and chemical
bonds which cannot be seen by the naked eye. In each experiment, a student can
interact with the haptic device and complete the experiment steps as in a real lab, what
they called in chemistry macroscopic level. At the macroscopic level, a user can use
physical movements to move and rotate glassware and chemical substances to act and
perform experiments steps as in a real lab. Then, the user can zoom into the chemical
compounds and see and interact with virtual representations of molecules and
chemical bonds, what is called in chemistry, the microscopic level. At the microscopic
level, the system shows the interaction between molecules due to the electric field
around them and its features and allows the user to interact with atoms and molecules
using haptic technology. At the microscopic level, the user can use gestures to rotate
the 3D molecular models of the chemical compounds and explore the 3D structure.
The following subsection describes an experiment that can be executed with the
system.
3.1</p>
      <p>Salt Hydrolysis Experiment</p>
      <p>The objective of this lab is to study the change of three different types of salts
when they are added to water, chemically called Salt Hydrolysis. Our system allows
the user to select one of three different types of salts - ammonium chloride salt,
sodium nitrate salt or potassium fluoride salt. Each one of these salts gives a different
result when they are added to water. At the macroscopic level of the system, the user
completes the experiment steps using the haptic device and then the change can be
observed in the mixture’s appearance as in a real lab. The chemical explanation of this
change can then be discovered by moving to the microscopic level which can help
deliver a better understanding of this chemical reaction.</p>
      <p>Fig. 1: A student using the haptic system (a) The student pouring the universal
indicator solution into the water beaker; (b) The student tapping the screen remotely using the</p>
      <p>Leap Motion to move to the microscopic level.</p>
      <p>
        Ammonium Chloride Salt. At the macroscopic level, when the universal indicator
solution is added to the water beaker and the mixture is stirred through interaction
with the haptic device, the color of water changes to green. Then, ammonium chloride
salt (NH4Cl) is added to the water beaker, as shown in Fig. 2 (a). As in Fig. 2 (b), the
color of the mixture turns to yellow when it is mixed using a glass rod, which means,
chemically, an acid is formed [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ]. At the microscopic level, ammonium chloride
dissociates in water into ions. These ions react to produce ammonium hydroxide
(NH4OH) and hydrochloride acid (HCl). In this case, the net result is a relative excess
of hydrogen ions, giving an acid solution which causes changing the solutions color to
yellow [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ].
      </p>
      <p>
        Sodium Nitrate Salt. As in the macroscopic level of the previous lab, the
universal indicator solution is mixed with the water. However, when sodium nitrate salt
(NaNO3) is added to the water beaker and mixed using the Leap Motion controller,
the color of the mixture does not change because a neutral solution is formed. At the
microscopic level, 3D visualization of the water molecule and the sodium nitrate
molecule is shown as in Fig. 3 (a). When the user adds the water molecule to the sodium
nitrate molecule, the sodium ion reacts with the hydroxide ion to produce sodium
hydroxide (NaOH), which is a strong base, whereas the nitrate ion reacts with
hydrogen ion to produce nitric acid (HNO3), which is a strong acid [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ]. In this case, the
net result is a neutral solution which keeps the color of the solution constant, as
shown in Fig. 3 (b).
Potassium Fluoride Salt. Potassium fluoride salt (KF) is added to the water
beaker which has been already mixed with the universal indicator solution. The color
changes to blue, which means that chemically a base is formed. Then, the user taps
the screen remotely to explore the result compound and goes from the macroscopic
level to the microscopic level. At the microscopic level, 3D representations of water
and potassium fluoride molecules are displayed. When the user uses the haptic system
to add the water molecule to the potassium fluoride molecule, ions react and produce
potassium hydroxide (KOH) and hydrofluoric acid (HF). In this case, the net result is
giving a basic solution which causes changing the solutions color to blue [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ].
(a)
(b)
      </p>
      <p>This paper introduces a molecule virtualization system and virtual labs along with
the haptic interface implemented within it. In reference to the above examples, our
educational system combines two approaches to the study. Thus, students will be able
to apply lab phases in a virtual lab environment and molecular structures by only
downloading the system and plugging in the Leap Motion controller. The virtual
reality along with haptic technology allows a user to visualize and compute complex data
in simulated environments.
We believe that this kind of application have the potential to complement
traditional e-learning delivery, particularly in conjunction with organized teaching structures
such as MOOCs. The MOOC educational format has the possibility to reach several
people in every part of the world, however, in many cases it is difficult to properly
engage followers in hands-on learning activities. With the help of interactive systems,
students might complement theoretical knowledge with practical ability. This is
especially important for disciplines like chemistry, discussed here as an example, in which
theory and practice are deeply entangled. Moreover, besides the facilitation of
concepts acquisitions, the presented system have the potential to complement traditional
e-learning assessment procedures, which are almost entirely based on testing the
knowledge of the user through tests and questionnaires, by focusing on practical
abilities, other than theoretical.</p>
      <p>In future works, more effort would be required to enhance and improve the
visualization interfaces. Future directions of the work would require to cover more and
various types of chemical subjects. As a future extension, more efforts would be required
to evaluate the system using cognitive knowledge tests. It also would require to be
applied in educational environments and gather opinions and suggestions from
students and instructors which could be used to make the system more effective.</p>
    </sec>
  </body>
  <back>
    <ref-list>
      <ref id="ref1">
        <mixed-citation>
          1.
          <string-name>
            <surname>Jones</surname>
            ,
            <given-names>M.G.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Bokinsky</surname>
            ,
            <given-names>A.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Andre</surname>
            ,
            <given-names>T.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Kubasko</surname>
            ,
            <given-names>D.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Negishi</surname>
            ,
            <given-names>A.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Taylor</surname>
          </string-name>
          , R.,
          <string-name>
            <surname>Superfine</surname>
          </string-name>
          , R.:
          <article-title>Nanomanipulator applications in education: the impact of haptic experiences on students attitudes and concepts</article-title>
          , (
          <year>2002</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref2">
        <mixed-citation>
          2.
          <string-name>
            <surname>Deci</surname>
            ,
            <given-names>E.L.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Ryan</surname>
            ,
            <given-names>R.M.:</given-names>
          </string-name>
          <article-title>The support of autonomy and the control of behavior</article-title>
          .
          <source>J. Pers. Soc. Psychol</source>
          .
          <volume>53</volume>
          ,
          <issue>10241037</issue>
          (
          <year>1987</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref3">
        <mixed-citation>
          3.
          <string-name>
            <surname>Barfield</surname>
            ,
            <given-names>W.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Danas</surname>
          </string-name>
          , E.:
          <article-title>Comments on the use of olfactory displays for virtual environments</article-title>
          .
          <source>Presence Teleoperators Virtual Environ</source>
          .
          <volume>5</volume>
          ,
          <issue>109121</issue>
          (
          <year>1996</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref4">
        <mixed-citation>
          4.
          <string-name>
            <surname>Waldrop</surname>
            ,
            <given-names>M.M.:</given-names>
          </string-name>
          <article-title>Education online: The virtual lab</article-title>
          .
          <source>Nature</source>
          .
          <volume>499</volume>
          ,
          <issue>268270</issue>
          (
          <year>2013</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref5">
        <mixed-citation>
          5.
          <string-name>
            <surname>Chapanis</surname>
            ,
            <given-names>A.</given-names>
          </string-name>
          : Words, Words, Words.
          <source>Hum. Factors J. Hum. Factors Ergon. Soc. 7</source>
          ,
          <issue>117</issue>
          (
          <year>1965</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref6">
        <mixed-citation>
          6.
          <string-name>
            <surname>Katz</surname>
            ,
            <given-names>D.</given-names>
          </string-name>
          : The world of touch. Erlbaum, Hillsdale, NJ (
          <year>1989</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref7">
        <mixed-citation>
          7.
          <string-name>
            <surname>Sathian</surname>
            ,
            <given-names>K.</given-names>
          </string-name>
          :
          <article-title>Practice makes perfect: Sharper tactile perception in the blind</article-title>
          .
          <source>Neurology</source>
          .
          <volume>54</volume>
          ,
          <issue>22032204</issue>
          (
          <year>2000</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref8">
        <mixed-citation>
          8.
          <string-name>
            <surname>Lukjanska</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          :
          <article-title>Usability evaluation of a haptic-based framework for chemistry education</article-title>
          , (
          <year>2010</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref9">
        <mixed-citation>
          9.
          <string-name>
            <given-names>Leap</given-names>
            <surname>Motion</surname>
          </string-name>
          <article-title>| 3D Motion and Gesture Control for PC &amp; Mac</article-title>
          , https://www.leapmotion.com/product.
        </mixed-citation>
      </ref>
      <ref id="ref10">
        <mixed-citation>
          10.
          <string-name>
            <surname>Barfield</surname>
            ,
            <given-names>W.:</given-names>
          </string-name>
          <article-title>The use of haptic display technology in education</article-title>
          .
          <source>Themes Sci. Technol</source>
          . Educ.
          <volume>2</volume>
          ,
          <issue>1130</issue>
          (
          <year>2010</year>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref11">
        <mixed-citation>
          11.
          <string-name>
            <surname>Petrucci</surname>
            ,
            <given-names>R.H.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Harwood</surname>
            ,
            <given-names>W.S.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Herring</surname>
            ,
            <given-names>G.F.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Madura</surname>
          </string-name>
          , J.D.:
          <article-title>General chemistry: principles and modern applications</article-title>
          . Pearson Prentice Hall (
          <year>2010</year>
          ).
        </mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>