We propose to integrate diffractive axicons into solar cells as a light trap for increasing of light absorbing efficiency. Experimental work and numerical simulations are provided in this paper. The experimental measurements of light-to-electricity conversion efficiency are conducted using a laser with tunable wavelength.
The latest days increasing of efficiency and decreasing of the cost can be noticed in
the solar power engineering development. It is providing a significant growth of
photovoltaic energy production and solar cells manufacturing [
Thus, solar cells efficiency increasing methods development is a relevant problem at present. There are two problem classes of light-to-electricity conversion efficiency. The first is the problem of efficiency increasing of light transportation to an active semiconductor (optical efficiency problem). And the second one is the problem of efficiency increasing of the delivered light conversion into electric current (quantum efficiency problem).
There is a review in the paper [
After analysis of optical efficiency increasing methods we can conclude that the
integration of diffractive gratings and solar cells is the inexpensive and appropriate
approach to efficient solar cells manufacturing.
These elements can be manufactured with inexpensive nanoimprint lithography [
Thus, it seems to be relevant to use arrays of diffractive microaxiconical structures
which are etched in front surface of a solar cell. These diffractive structures serve at
the same time as an antirelfecting and focusing structure, also it scatters light inside of
active semiconductor due to diffraction and hence elongates the optical path and
increases quantum efficiency of light-to-electricity conversion. The Kirchhoff
diffraction integral is used to calculate the spatial distribution of the optical field in the focal
region of an optical element in the paper [
In this work we describe the research of diffractive axicons utilizing opportunity for solar cells efficiency increasing. 2
It is well known that diffractive axicon transforms initial plane wave front into conical
wave surface which converges towards the optical axis z at angle α (fig. 1). Thus,
onaxis light segment which has a full width at a half maximum of равна 0,36λ/NA ( is
a wavelength, NA = sin – numerical aperture of the axicon), that is significantly less
than Airy disk diameter which is produced with a lens with the same numerical
aperture [
In figure 2 there are calculated energy patterns of light propagation through axicons with high numerical aperture. In this figure we can see that the length of on-axis light segment is becoming shorter and light is scattered at higher angles with increasing of numerical aperture. In addition, from figure 3 we can derive that light scattering intensifies with increasing of the wavelength.
Fig. 2. Calculated intensity patterns whereas light propagates through the axicon with various numerical aperture a) NA=0.71, b) NA=0.87, c) NA=0.95 Fig. 3. Transverse patterns of light diffraction on the axicon near the axicon surface for different wavelength of incident light: a) 532 nm, b) 633 nm Thus, axicons can increase efficiency of light capturing due to high-angle scattering of normally impinging light.
In figure 4 we propose a way of combining a diffractive axicon and a solar element. The axicon is placed at the front surface of the solar cell. The axicon scatters impinging light and hence it elongates the optical path of the rays. It must increase the possibility of photon capturing inside the active medium. This section describes conducted numerical simulation of the light absorbing in solar cell active semiconductor. The simulation is based on Helmholtz equations solving with finite element method using Comsol Multiphysics software. In this paper we consider only 2d model.
General view of simulation layout is shown in figure 5. Plane wave illuminates the solar cell element from above then light passes through the thin glass layer, active silicon medium and then reflects from the bottom silver layer. The thickness of the silicon layer is 1 µm, silver layer is 40 nm thick, and glass substrate is 1.8 µm thick. Diffractive grating relief height is 300 nm.
Plane wave origin is set in the top side of calculation domain. Lateral sides satisfy Bloch conditions which provide periodicity of the grating. Thus, the calculation domain is one period of diffractive grating.
Intensity distribution from figure 5a corresponds to standing wave.
Absorption spectrum is calculated as a following way. We calculate intensity distribution in all defined domain for a list of wavelength from 300 nm to 900 nm with the step of 5 nm. Then, for every wavelength we integrate the intensity in the area of active domain. The meaning of mentioned above integral is taken as a meaning of absorption.
In the figure 6 there are absorption spectrums for a solar sell that is covered by glass plate and also glass diffractive grating.
We can see, that spectrums significantly differ from one another. Diffraction grating makes the absorption about ten times higher for the wavelength of 585 nm. This fact can be utilized for increasing of solar cell efficiency.
We should remember that a solar cell is illuminated with multispectral natural light with complex spectrum profile. Thus, it has to be noticed that for one wavelength diffractive grating increase the efficiency, but it does not have to work for another wavelength. Hence, the research of multispectral absorption increasing with grating needs to be provided more careful. We set an optical layout which is shown at figure 7. We use laser with a tunable wavelength EKSPLA NT242 as a light origin. This laser can produce a beam with a wavelength from the range from 195 nm to 2600 nm. The mirror M reflects laser and redirects it into the combination of diffractive axicon and the solar cell. The axicon is placed to the front surface of the solar cell. Using electro-multimeter V we measure a current which is generated with the solar cell. Fig. 7. Experimental setup for measuring of voltage in solar cell circuit. Laser – laser with a tunable wavelength EKSPLA NT242, M – mirror, A – diffractive axicon, SC – solar element,
V – electro-multimeter In conducted experiments we measure a current in the solar cell circuit combining with a glass substrate at the first series of measurements and with diffractive axicon with period of 2 µm in the second series of measurements.
Scanning Electronic Microscopic photograph of the axicon is shown in the figure 8a, in figure 8b we show intensity pattern at the distance of few microns from the axicons surface under illumination of light with the wavelength of 633 nm. Intensity distribution from figure 8b was experimentally measured with near-field microscope. The axicon has numerical aperture NA = 0.32.
Fig. 8. General view of central part of the axicon a) and experimentally measured diffractive intensity pattern in near field The measured meanings are shown in table 1. From the table we can derive that combination of the solar cell and axicon provides voltage increasing in the range from 400 nm to 800 nm.
Conducted experiments show advantages of diffractive axicon using for increasing of solar cells efficiency.
Numerical simulations of absorption spectrum qualitatively show benefits of diffractive axicon using for absorption increasing.
In future we are planning to provide more detailed research of dependence of solar cells quantum efficiency on different periods (including subwavelength) of diffractive axicons which are combined with the solar element.
This work was funded by Russian Scientific Fund (grant No. 14-31-00014).