=Paper= {{Paper |id=Vol-1900/paper2 |storemode=property |title=Cold mirror based on High-Low-High refractive index dielectric materials |pdfUrl=https://ceur-ws.org/Vol-1900/paper2.pdf |volume=Vol-1900 |authors=Vadim Elyutin,Muhammad A. Butt,Svetlana N. Khonina }} ==Cold mirror based on High-Low-High refractive index dielectric materials == https://ceur-ws.org/Vol-1900/paper2.pdf
Cold mirror based on High-Low-High refractive index dielectric materials
                                                V.V. Elyutin1, M.A. Butt1, S.N. Khonina1,2
                                    1
                                    Samara National Research University, 34 Moskovskoe Shosse, 443086, Samara, Russia
2
 Image Processing Systems Institute – Branch of the Federal Scientific Research Centre “Crystallography and Photonics” of Russian Academy of Sciences, 151
                                                      Molodogvardeyskaya st., 443001, Samara, Russia




Abstract

In this paper, a design for a multilayer dielectric cold mirror based on TiO 2/ SiO2 and TiO2/MgF2 alternating layers is presented. A cold mirror
is a specific dielectric mirror that reflects the complete visible light spectrum whereas transmitting the infrared wavelengths. These mirrors are
designed for an incident angle of 45o, and are modeled with multilayer dielectric coatings similar to interference filters. Our designed mirror
based on TiO2/SiO2 shows an average transmission of less than 5 % in the spectrum range of 425- 610 nm whereas it has an average
transmission of 95 % in the spectrum range of 710-1500 nm.

Keywords: Cold mirror; TiO2; MgF2; SiO2; dielectric materials


1. Introduction

   Thin film optics is a well-developed technology and many devices such as passband filters, stopband filters, polarizers and
reflectors are successfully developed with the help of multilayer dielectric thin films [1-4]. These optical elements comprise of
alternating layers of high and low refractive index materials with specific thicknesses and awareness of their refractive index and
absorption. Multilayer dielectric filters are based on the principle of multiple reflections that takes place between the interfaces
of high and low index materials. Distributed Bragg Reflectors (DBRs) are one of the widely used filters which are quarter wave
thick of the center wavelength. The high reflection region of a DBR is known as the DBR stopband and can be obtained by the
refractive index contrast between the constituent layers [5]. A cold mirror is a specific dielectric mirror that reflects the visible
light spectrum while transmits the infrared wavelengths. These mirrors work on the principle of multiple reflections between
high and low index material interface. The visible spectrum of light spans ~380-770 nm and the region beyond 770 nm in the
near infrared, which is heat. Radiations from a tungsten lamp contain at least six times as much heat as useful light in the visible
spectrum. The term cold light defines the radiation in which the IR spectrum is removed [6].
   A hot mirror is just the opposite of cold mirror which is designed to reflect infrared region while transmits the visible portion
of the beam. These mirrors can separate visible light from UV and NIR which helps in separating the heat from the system as
shown in figure 1. Cold mirrors have many practical applications such as in projectors, copy machines, medical instruments and
fibre optical illuminations [6, 7].




                                                                                   Visible                     IR-
                                                                                    light                   radiation



                                                  Light
                                                  source




                                                              Fig. 1. Schematic of a cold mirror.

2. Theoretical basis of multilayer structure

  Consider a multilayer dielectric system surrounded by an environment. Light from the source falls on the system at an angle
α0. For this purpose, wave front can be considered as planar. To calculate the spectral transmittance and reflectance intensity for
the p- and s-polarized light, matrix method is used:

                nm 2
    Ts ( )                  )  rs
                                        2
                   ts   , Rs (              ,
                no                                                                                                                                    (1)

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                                                Computer Optics and Nanophotonics / V.V. Elyutin, M.A. Butt, S.N. Khonina
           n     2               2
  Tp ( )  m t p , R p ( )  rp ,
           no                                                                                                                (2)

where ts, rs — amplitude transmission and reflection coefficients of the multilayer interference system for s-polarized light
whereas tp, rp — transmission and amplitude reflection coefficients for p-polarized light. Now, we will only consider s-
polarization because equations for both s and p polarization are related till equation (7). Amplitude coefficients are determined
from the following equations:

                           2no
  ts                                              ,
         no m11s  ino nm m12 s  im21s  nm m22 s                                                                              (3)


         no m11s  ino nm m12 s  im21s  nm m22 s
  rs                                              ,
         no m11s  ino nm m12 s  im21s  nm m22 s                                                                              (4)

where n0, nm – the effective refractive indices of the substrate and the environment, respectively; m i, js – elements of the
characteristic matrix Ms for s-polarized light:

        m             im12 s 
  M s   11s                   M 1s M 2 s M 3 s .....M q 2 s M q 1s M qs ,
         im21s        m22 s                                                                                                   (5)

q – Number of layers.

                              M (k  1, q)
In the expression (5) matrices k            determine the properties of each individual layer of the optical filter. Filter design
needs layers with high and low refractive indices. Therefore, the spectral characteristics are described by matrices multiplying:

                               i                                                i          
             cos(1 )             sin(1 )                          cos(2 )        sin(2 ) 
   M 1                      n1
                                           ,              M 2                 n2
                                                                                              ,
           in sin( )          cos(1 )                         in sin( )     cos(2 ) 
           1       1                                              2       2



                           i                                               i        
            cos(q 1 )         sin(q 1 )                     cos(q ) n sin(q ) 
  M q 1                 nq 1
                                             ,              Mp              q       ,                                       (6)
            in sin( )      cos(q 1 )                        in sin( ) cos( ) 
            q 1     q 1                                        q       q       q   

where φk – phase thickness for s- polarized light, which is calculated by the following equations:

         2                               2
  1         n1h1cos(1 ),        2          n 2 h 2cos( 2 ),
                                          

           2                                     2
  q1           n q1h q1cos( q1 ), q           n q h q cos( q ),
                                                                                                                              (7)

where hk – the physical thickness of the layers, nm; αk – the angles of refraction in the layers; nk – effective indexes refractive of
the layers which depends on the wavelength. In this case, the angle of refraction in the layers is 45 degrees, relative to the
normal.

  The main difference in calculations between s- and p- polarized light is specified in (8) and (9) equations.

  n1s  n1cos(1 ),         n 2 s  n 2 cos( 2 ),
                                                                                                                                (8)

  n1 p  n1 / cos(1 ), n 2 p  n 2 / cos(2 ),                                                                                 (9)

  The angle of refraction in the layers is calculated by the equations (10).



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                  n2                                   n2               
  1  arccos  1  o2 sin 2 ( o )  ,  2  arccos  1  o2 sin 2 ( o )  ,
                  n1                                   n2                                                                          (10)
                                                                        

  Transmission of an unpolarized light is calculated as an average of T s and Tp:

     1
  T  (Ts  Tp ),                                                                                                                      (11)
     2

  By using these equations, the transmission spectrum of the multilayer TiO 2/MgF2 filter was plotted with the help of Java
programing along with the transmission spectrum generated by commercially available open source filter Open filter. Their
response is fairly comparable as shown in figure 2.


                                             100
                                              90
                                              80
                                              70
                                              60
                                        %




                                              50
                                                                                 Modeled by Java program
                                              40
                                                                                 Modeled by Open filter software
                                              30
                                              20
                                              10
                                                0
                                                       500       625        750        875     1000      1125      1250

                                                                     Wavelength (nm)
                     Fig. 2. Transmission spectrum of cold mirror modeled by Java programming and open source software: Open filter.


3. Filter design

   In the designing of optical filters, the behaviour of the total multilayer system is estimated on the basis of the properties of the
individual layers in the stack [8]. Therefore to achieve the optimum performance, it is significant to optically characterize and
accurately determine the thickness of the individual layers. In this work, cold mirrors are designed in the wavelength range of
425-1500nm by using open source software Open Filter to selectively pass the wavelengths of interest and rejecting the
undesired wavelengths in the visible spectrum. TiO2, SiO2 and MgF2 materials are carefully selected based on their high and low
refractive indices, respectively. TiO2 is a vital dielectric material with a wide band-gap energy and high refractive index that can
make it useful in the fabrication of multilayer thin films due to its high optical properties. For instance, its high transmittance
and high refractive index in the visible region (380-760 nm) make it valuable to be employed in the production of the optical
filter and window glazing [9, 10]. Layers made of oxides are harder than those made of fluorides, sulphides or semiconductors.
Thus, they are ideal to be used on exposed surfaces. Semiconductor materials should be avoided in filters which have to be used
over a wide range of temperatures because their optical constants can change considerably. The open filter uses transfer matrix
method to analyze the transmission and reflection of light from layers based on thickness and type of materials. Designs are
optimized to maximum the transmission required at wavelengths using needle synthesis method (addition of thin layers called
needle and analyze transmission till the best results obtained) [11]. The thicknesses of the layers for cold mirror based on
TiO2/MgF2 and TiO2/SiO2 are shown in table 1. Both mirrors have 20 layers with almost comparable total thickness. Special
attention has been given to keep the thickness of the filters within economic limits.
   Assuming the incident angle of un-polarized light equals 45o, these mirrors have reflective properties in the spectral range
from 425-610 nm and 710-1500 nm up to 95 % and 5 %, respectively as shown in figure 3. For all dielectric stack filters, the
transmission depends on the angle of incidence. The central wavelength of the FP filter shifts toward the smaller wavelengths as
the angle of incidence is increased. When the incident angle of light decreases from 45 o to 0o the transmission spectrum shifts
from 710 to 750 nm.


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                                       Computer Optics and Nanophotonics / V.V. Elyutin, M.A. Butt, S.N. Khonina
4. Conclusion

   In this work, we presented the modeling results of cold mirrors based on TiO2/MgF2 and TiO2/SiO2 for 45o of un-polarized
incident light by using java programming and commercially available Open source software Open filter. Both mirrors show the
reflection of 95% in the spectral range of 425-610 nm and 95% of transmission in the spectral range of 710-1500 nm. The
designs are optimized to maximum the transmission required at wavelengths using needle synthesis method. We observed a right
shift in a spectrum when the angle of incidence of light was reduced from 45 o to 0o.

                                   Table 1. Layer thicknesses of TiO2/MgF2 and TiO2/SiO2 based Cold mirrors.
                                    Layer no. Material Thickness (nm) Layer no. Material Thickness (nm)
                                        1          TiO2             14            1          TiO2           25
                                        2          MgF2            114            2          SiO2          121
                                        3          TiO2             45            3          TiO2           55
                                        4          MgF2             84            4          SiO2           82
                                        5          TiO2             62            5          TiO2           55
                                        6          MgF2             71            6          SiO2           65
                                        7          TiO2             43            7          TiO2           44
                                        8          MgF2             87            8          SiO2           99
                                        9          TiO2             44            9          TiO2           51
                                       10          MgF2            107           10          SiO2          110
                                       11          TiO2             66           11          TiO2           71
                                       12          MgF2             90           12          SiO2           92
                                       13          TiO2             68           13          TiO2           72
                                       14          MgF2            130           14          SiO2          123
                                       15          TiO2             48           15          TiO2           54
                                       16          MgF2            118           16          SiO2          106
                                       17          TiO2             87           17          TiO2           93
                                       18          MgF2             54           18          SiO2           53
                                       19          TiO2             79           19          TiO2           80
                                       20          MgF2            228           20          SiO2          218
                                       Total thickness            1639           Total thickness          1669

                                     100
                                      90                                      Passband

                                      80
                                      70                             Transmission spectrum of TiO /MgF mirror
                                                                                                 2    2
                               (%)




                                      60                             Transmission spectrum of TiO /SiO mirror
                                                                                                 2    2
                                            Reflected                Reflection spectrum of TiO /MgF mirror
                                      50                                                       2    2
                                            band
                                                                     Reflection spectrum of TiO /SiO mirror
                                                                                               2    2
                                      40
                                      30
                                      20
                                      10
                                       0
                                           450      600       750       900       1050       1200       1350    1500

                                                             Wavelength (nm)
                            Fig. 3. Transmission and reflection spectrum of the cold mirror in the wavelength range of 425-1500 nm.

Acknowledgements

 This work was supported by the Ministry of Education and Science of the Russian Federation and the Russian Foundation for
Basic Research (grant No. 16-29-11698-ofi_m, 16-29-11744-ofi_m).

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