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    <article-meta>
      <title-group>
        <article-title>Research for the Exhaust Gas at Natural Gas Combustion Hobs</article-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <string-name>Ioannis Betounis</string-name>
          <xref ref-type="aff" rid="aff0">0</xref>
        </contrib>
        <aff id="aff0">
          <label>0</label>
          <institution>Private research</institution>
          ,
          <addr-line>Sarafi 29, Larissa, 40200</addr-line>
          ,
          <country country="GR">Greece</country>
        </aff>
      </contrib-group>
      <fpage>127</fpage>
      <lpage>133</lpage>
      <abstract>
        <p>The present research was conducted in order to investigate the accuracy of the measurements carried out in the combustion hobs with natural gas fuel. An important conclusion about the exhaust gas in the combustion hobs with natural gas, independently harmonized or not with the Greek legislation, is that the wall-mounted boilers are given to the atmosphere more CO per KW than the classic floor-standing boilers. Another conclusion about the technicians, is that 26.3% of them do not have the necessary license, 19.3 % of them do not have an exhaust gas analyzer at all, but the 70.2 % of them use an exhaust gas analyzer on the first start and on the maintenance this percent drops down to 52.7 %.The conclusions show us that we have to take action about the exhaust gas limits of the wall-mounted boilers and also about the technical people.</p>
      </abstract>
      <kwd-group>
        <kwd>Natural gas</kwd>
        <kwd>measurements</kwd>
        <kwd>exhaust gas</kwd>
        <kwd>combustion hobs</kwd>
      </kwd-group>
    </article-meta>
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  <body>
    <sec id="sec-1">
      <title>1. Introduction</title>
      <p>Based on Greek legislation, the choice of combustion hobs with natural gas was made because they
must issue an official exhaust gas control sheet during the first start. This obligation to issue an exhaust
gas control sheet at the beginning is not required for combustion hobs that work with other fuels in the
Greek market. From the data collected for the research, it was found that the measurements of the
exhaust gases written on the control sheets are not always correct and accurate. This is mainly due to
the fact that some wall-mounted boilers circulating in the Greek market, in their manufacturer's
technical manual, have delimited some of the measurement values in the exhaust gases, higher than the
Greek legislation. Also, during the collection of data for the research, it was found that measurement
technicians used analyzers that did not perform all the required measurements.</p>
      <p>2022 Copyright for this paper by its authors.</p>
    </sec>
    <sec id="sec-2">
      <title>Conclusions for the Technicians</title>
      <p>From the data collected through the public poll, we can see that most technicians in Greece have the
necessary license with 73.7 % (Figure 1).</p>
      <p>Yes
No</p>
      <p>But this number does not agree with the question about the profession of the participants. In the
question about the profession 52.6 % answered that they are combustion technicians and 40.4 % are
mechanics (Figure 2). The Greek laws give the mechanics the license to provide maintenance services
for natural gas boilers when they finish university. Still, the combustion technicians give the license
after some years of proven experience in their occupation and after examinations. If all those technicians
had the license with the mechanics together would be 93.0 % of participants with the license. But
according to the previous question, only 73.7 % have a license. So, 19.3 % of technicians in Greece
provide maintenance services for natural gas boilers without the necessary license.</p>
      <sec id="sec-2-1">
        <title>Plumber Combustion technicians Mechanic</title>
        <p>The next questions are about the use of an exhaust gas analyzer. The first question was about if the
technicians had an exhaust gas analyzer, a critical tool for natural gas boilers that give technicians all
the necessary measurements to adjust the burner efficient. Using the exhaust gas analyzer from the
technicians is also critical in the first start or yearly maintenance to eliminate the risk of producing
harmful to the health exhaust gas. In this question 80.7 % answer that they have exhaust gas analyzer
and the rest of them dose not (Figure 3).</p>
        <p>The next two questions try to figure out the technician’s use of the exhaust gas analyzer. One
question was whether they use an exhaust gas analyzer at first start of a natural gas boiler, and the
second about whether they use it in the yearly maintenance of the natural gas boiler. The answer is yes
for the first start of a boiler pick up 70.2 % (Figure 4) and for the yearly maintenance pick up 52.7 %
(Figure 5). The answers show that technicians do not use the exhaust gas analyzer as they have to do to
ensure the efficiency of the boiler and the quality of the exhaust gas.</p>
      </sec>
      <sec id="sec-2-2">
        <title>I don’t have analyzer I don’t use Often use Always use</title>
      </sec>
    </sec>
    <sec id="sec-3">
      <title>2.1.1. Conclusions for the Boilers</title>
      <p>
        Another important conclusion about the exhaust gas in the combustion hobs with natural gas,
whether harmonized or not with the Greek legislation, is that the wall-mounted boilers are given to the
atmosphere more CO per KW than the classic floor-standing boilers. According to the data, the
wallmounted boilers have exhaust gas of 1.583 CO ppm per 1 KW, and the floor-standing boilers have
exhaust gas of 0.147 CO ppm per 1 KW. That means 10.76 times more CO ppm in the atmosphere.
Regarding the produced gas of NOx, the wall-mounted boilers have exhaust gas of 0.820 NOx ppm per
1 KW, and the floor-standing boilers have exhaust gas of 0.166 NOx ppm per 1 KW. The difference is
that the wall-mounted boilers produce 4,939 times more NOx than the floor-standing boilers. In the
following table (Table 1), we can see the total amount of the KW, the CO in ppm, and the NOx in ppm
of the two biggest natural gas boilers categories. CO is a highly toxic gas, and it can cause death. The
NOx can cause several problems in humans as breathing problems, headaches, chronically reduced lung
function, eye irritation, loss of appetite, and corroded teeth. The Greek law [
        <xref ref-type="bibr" rid="ref1">1</xref>
        ] about the exhaust gas
from natural gas burners limited the higher level of CO to 90 ppm and NOx to 150 ppm per boiler.
      </p>
    </sec>
    <sec id="sec-4">
      <title>2.1.2. Specifications of Burner Manufacturers</title>
      <p>
        The specifications of the burner manufacturers play a key role in the proper operation of the device.
Due to this, for the arrangements required for the proper operation of the combustion chamber, the
combustion technician takes the manufacturer's instructions first and then the Greek legislation. At the
first start of a wall-mounted boiler or in the yearly maintenance, the technician has to take measurements
of the exhaust gas and compare them with the specifications of the manufacturer of the boiler. From
small research done in the manuals of the manufacturers of wall-mounted boilers, it was found that the
manufacturers' requirements for efficient and proper operation of wall-mounted boilers in the exhaust
gases are higher than the limit values set by the Greek legislation [
        <xref ref-type="bibr" rid="ref1">1</xref>
        ]. For example, the following figures
6 and 7 are easy for someone to see that the manufacturer gives specifications higher than the Greek
legislation regarding carbon monoxide.
      </p>
      <p>In the next figure (Figure 7), we can see also see the limits are out of the Greek legislation.</p>
    </sec>
    <sec id="sec-5">
      <title>3. Conclusions</title>
      <p>From the data of the flue gas control sheets we can see that t the wall-mounted natural gas boilers
produce 10.76 times more CO than floor-standing boilers. Because of this, the manufacturers of the
wall-mounted boilers should correct the combustion parameters, to produce less CO. However,
according to the data from the manufacturers' manuals, of wall-mounted gas boilers the values of
produced CO are greater than the limit of Greek legislation. The state should intervene and create
control mechanisms that will check the wall-mounted boilers with appropriate methods, to see if they
are harmonized with the Greek legislation. The state also should give importance to the control of the
technicians who work with the boilers. Finally, the technicians should be forced to use analyzer during
the ignition and maintenance of a natural gas boiler, so that they can be adjusted correctly for more
efficient combustion and environmental protection.</p>
      <p>Farther research on combustion boilers, including all fuels, would give us a clearer picture for the
harmful gases that included in atmosphere. Also, farther information’s for the use of the flue gas
analyzer and the professional technical staff will be useful.</p>
    </sec>
    <sec id="sec-6">
      <title>4. Acknowledgements</title>
      <p>I want to thank the office of technical services in the municipality of Larissa and the technicians for
providing me the necessary data from the exhaust gas control sheets to do this research.
5. References</p>
    </sec>
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