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  <front>
    <journal-meta />
    <article-meta>
      <title-group>
        <article-title>Bio-Inspired Method for Advanced Industrial Sludge Treatment with Closed Cycle Drying Process</article-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author">
          <string-name>Filippo Rapisarda</string-name>
          <xref ref-type="aff" rid="aff0">0</xref>
        </contrib>
        <contrib contrib-type="author">
          <string-name>Riccardo Zammataro</string-name>
          <xref ref-type="aff" rid="aff1">1</xref>
        </contrib>
        <contrib contrib-type="author">
          <string-name>Giuseppe Di Lorenzo</string-name>
          <xref ref-type="aff" rid="aff2">2</xref>
        </contrib>
        <aff id="aff0">
          <label>0</label>
          <institution>4R Ecologia &amp; Costruzioni S.r.l.</institution>
          ,
          <addr-line>Chiaramonte Gulfi (RG)</addr-line>
          ,
          <country country="IT">Italy</country>
        </aff>
        <aff id="aff1">
          <label>1</label>
          <institution>Department of Electric, Electronics and Computer Engineering, University of Catania</institution>
          ,
          <addr-line>Catania</addr-line>
          ,
          <country country="IT">Italy</country>
        </aff>
        <aff id="aff2">
          <label>2</label>
          <institution>Euromecc S.r.l. S.S.</institution>
          ,
          <addr-line>Misterbianco (CT)</addr-line>
          ,
          <country country="IT">Italy</country>
        </aff>
      </contrib-group>
      <fpage>139</fpage>
      <lpage>146</lpage>
      <abstract>
        <p>- The article describes a new bio-inspired process for the Advanced Treatment of Industrial Sludge with a Closed Cycle Drying Process (TAFIPACC).This process represents an innovation in the way of treating sludge and other shovellable residues deriving from machining and widespread industrial processes in the largest industrial installations, such as refineries, steel mills, chemical plants, glass processing installations, cosmetics manufacturing facilities, pharmaceutical manufacturing plants, paper mills. The process starts from the use of mixers in the production of concrete, and makes a thermal contribution to the material during mixing stage, thus separating part of these substances directing them to an integrated process of fractional distillation. The article introduces "clean-up" as a new process through an innovative stage of evaporation and distillation in a closed cycle which is able to separate and collect pollutants and volatile components that would be otherwise dispersed into the atmosphere as in the case of more traditional methods of open-cycle sludge drying.</p>
      </abstract>
      <kwd-group>
        <kwd>- Industrial lime</kwd>
        <kwd>treatment</kwd>
        <kwd>pollution</kwd>
        <kwd>energy recovery</kwd>
        <kwd>environment</kwd>
        <kwd>distillation</kwd>
      </kwd-group>
    </article-meta>
  </front>
  <body>
    <sec id="sec-1">
      <title>I. INTRODUCTION</title>
      <p>Nowadays different industrial plant sludge treatment
methods are in use. The main ones are:</p>
      <p>
        - Centrifugation: it consists of separating water from sludge
by means of application of a centrifugal force[
        <xref ref-type="bibr" rid="ref1">1</xref>
        ];
      </p>
      <p>- Incineration: waste is eliminated by means of incineration,
with the scope of obtaining energy. Only 70% of the volume of
waste is eliminated with a subsequent ash disposal;
- Inerting - Stabilization: the process of making highly
critical rejection for consistency and chemical-physical
characteristics manipulatable and inhibiting the release of
contaminants. The set of the two mechanisms involves the
transformation of waste into an easily movable solid, with little
surface area exposed to the surrounding environment, inside
which the pollutants are trapped, stuck in insoluble
compounds;</p>
      <p>- Thermal Desorption: solid waste, such as soil and sludge,
is heated causing the vapourization of all those contaminants
characterized by a boiling point inferior to the heating
temperatures. The TAFIPACC method assembles by
integrating two types of processes closely related to each other:
inerting - stabilization / thermal desorption and combining</p>
    </sec>
    <sec id="sec-2">
      <title>Copyright held by the author(s).</title>
      <p>them into a single system. This means that the individual
process deficiencies may be reset in a single cycle. In the
TAFIPACC process, the treatment of a certain type of waste,
such as industrial sludge, will allow reducing its volume and
associated emissions, improving and minimizing the mobility
of contaminated elements present in them. The high costs of
numerous sludge treatment techniques currently in use have
triggered the development of alternative techniques such as the
one proposed. For the time being, it appears to be a more
economical solution, which significantly reduces the mobility
of pollutants resulting in less environmental impact.</p>
    </sec>
    <sec id="sec-3">
      <title>II. THE PROCESS</title>
      <p>
        TAFIPACC is a new automatic methodology for the
treatment of polluted sludge that puts at the centre of the
process 3 mc planetary mixers made of vibrated concrete [
        <xref ref-type="bibr" rid="ref2">2</xref>
        ]
flanked by a series of devices that allow the extraction of the
volatile portion of the worked refusal.
      </p>
      <p>Such a machine will be equipped, on the underside, with a
device for heating, which has never before been applied to a
concrete mixer. It allows a desired increase of the temperature
of the content within the mixing tank, causing the evaporation
of volatile substances so that they separate from the sludge
during treatment.</p>
      <p>The functionality of this device implies the use of the
heated air that will be made circulate in a cavity created around
the mixing tank. The flow and temperatures will be regulated
so as to control the thermal increments (critical factor under
study).</p>
      <p>Flanked to the mixer, an air recirculation circuit will be
arranged. A high prevalence ventilator will suck up the air
filled by vapour emitted from the mixing and heated sludge.</p>
      <p>The air is then pushed through the radiators of two heat
pumps. In its recirculation the air will pass from the first
radiator, where the less volatile part of the vapour will
condense to extract almost clean water.</p>
      <p>The air will then pass from the second, cooler radiator
enabling condensation of the most volatile elements, i.e.
hydrocarbons at increased pollutant content to confer on the
dedicated disposal. By doing this, it is avoided that these
hazardous pollutants (e.g. harmful hydrocarbons, Benzene,
Fluorene, Pyrene, etc.), may be dispersed into the atmosphere,
as is the case in many traditional systems for industrial sludge
drying which inflict great damage for the environment. In these
first two radiators the initial hot air will cool; crossing the hot
radiators of heat pumps it will regain temperature before
returning into the mixer, obtaining indeed an energy
recovery. Before entering the mixer, the fluid will pass through
a rolling valve which will decrease the pressure inside the
mixer (facilitating the evaporation) and increase pressure in the
branches of the closed cycle where radiators are located (thus
facilitating condensation in cold radiators).</p>
      <p>A bag filter that saves impurities and dust entrance presides
over the cleaning of this condensation line.</p>
      <p>The mixer will also be equipped with a moisture detection
probe that, by sending data to the supervising automation
device, will allow constant monitoring of the drying progress
and automatically maintain the determined values of residual
moisture.</p>
      <p>The machine will be sized to treat the quantity equal to 3
ton / h of polluted sludge and consequently produce 3 mc / h of
high quality vibrated concrete, therefore it is suitable to be
applied (using appropriate equipment available on the market)
for the packaging of different kinds of high quality goods (e.g.
tiles, building blocks, interlocking paving, heavy blocks for
various uses, etc.). This places an added value to the sludge
treatment process with a profitable use of the output material.
To treat 3 tons of sludge, around 4.7 tons of clean inert and 0.6
tons of cement will be used.</p>
      <p>These are the initial reference values that will be tested and
optimized during the research. By treating 3 tons of sludge it is
supposed that 30% of the liquid part from the sludge will be
extracted by the circulation of air in the distillers. Of this liquid
part, the desired goal is to obtain 50% clean and immediately
usable water and the other 50% of water assigned to an
integrated module in the prototype dedicated to the treatment of
liquids with high content of pollution, whereas the residual
water will be recovered by separating any contaminants present
in it.</p>
      <p>The TAFIPACC method, as the result of the combination
of two types of sludge treatment (inerting - stabilization /
thermal desorption) into a single system, permits a significant
reduction of costs. Moreover, this proposed alternative
technique is not only more economically advantageous but also
minimizes the mobility of pollutants resulting in a lower
environmental impact.</p>
    </sec>
    <sec id="sec-4">
      <title>The structure of the mixer consists of two parts: 140</title>
      <p>
</p>
      <p>The power plant where the epicyclic reduction
locates (Fig.2a);
The mixing tank with a 4 m diameter (Fig. 2b).</p>
      <p>(a) Power plant; (b) Mixing tank.</p>
      <p>The electric motor, placed above the reducer cap, through
an epicyclic water seal reducer and gears transmission,
transfers the movement to the mixing equipment.</p>
      <p>Every motor is connected to its own reducer which presents
sprocket wheel which in turn gets started with the fifth wheel,
namely a type of axial bearing for low rotational speed and
high axle load applications. The fifth wheel is composed of an
internal ring, fixed to the power loom, and the external slip ring
supporting the whole disk.</p>
      <p>To the plate carrier, bottomed scraping shovels, of side, and
mixing stars are fixed.</p>
      <p>The latter are joint to the fifth wheel so to be consequently
dragged with the rotation of the second, which rotating around
its own reference axis gears with the fixed crown.</p>
      <p>The inferior part of the mixer consists of a mixing tank with
an opening at the bottom closed by a rotating hatch whose
automate opening occurs by means of a hydraulic cylinder
once the mixing stage of concrete has finished.</p>
      <p>This is hinged in its axis which rotates inside the sleeve.
For this reason, the axis and its relative bearings must be
suitably measured.</p>
      <p>In order to get the tank sizing, some calculations based on
''soft output volume'' which indicates the finished product
which derives from the conclusion of the manufacturing cycle
and ''vibrating output volume'' which is the volume of the
sleeve once it is implemented and thus vibrated, have been
made.</p>
      <p>
        Once the broad measures of the tank, and hence of the
hatch, were stated, the measures of the hydraulic piston and
supports, the fixed one (tank side) and the mobile one (hatch
side), were determined assuring the correct alignment among
these, thus avoiding transverse forces components which cause
an early wear of the scroll bushing of the shank [
        <xref ref-type="bibr" rid="ref3 ref4">3, 4</xref>
        ].
      </p>
      <p>By considering the exercise pressure as equal to 180 bar,
the tangential force was calculated per unit lengh, which acts
on the outer edge of the hatch through the balance of the
moments with regard to the pole consisting of the axis of the
hatch (Fig. 3).</p>
      <p>Forces acting on the hatch.</p>
      <p>For a watertightness of the tank, seals in polieuretano
lodging on the contact surfaces of the tank and hatch are
arranged. These, going through with a creeping contact, are
subject to wear, hence the necessity of evaluating the tension
degree (4) necessary to ensure tightness, avoiding excesses
which cause an early wear of seals. In the solution of the
matter, in addition to material, profile shape and the
interference degree (5) between the fixed part (the tank) and
the moving part (the hatch) of the seals couple play a leading
role.</p>
      <p>The door is supported by the shaft sized to withstand the
stresses due to the weight of the concrete and the forces
induced by the opening cylinder.</p>
      <p>
        The shaft has a variable diameter along the axis due to the
shoulders for the bearings, for which the correct coupling
tolerance has been obtained [
        <xref ref-type="bibr" rid="ref7">7</xref>
        ].
      </p>
    </sec>
    <sec id="sec-5">
      <title>IV. THE PACKAGING OF THE CONCRETE</title>
      <p>
        One of the techniques currently employed for inerting
dangerous sludge is packaging in concrete containers for
recycling as an aggregate [
        <xref ref-type="bibr" rid="ref8">8</xref>
        ].
      </p>
      <p>In this way the pollutants present in the sludge are
incorporated in the cement matrix at high strength avoiding the
reaction with the atmospheric agents and enter the
environmental life cycle.</p>
      <p>Depending on sludge composition, hydrated lime which
acts as a disinfectant and contrasts the odoriferous waste
components can be used.</p>
      <p>Since the proposed waste treatment process presupposes the
use of concrete packaging, a reference to the guidelines for its
production must be made. In order to obtain common medium
strength and consistency, a cubic meter of concrete is
composed of:
- Sand 720 kg
- Crushed 1280 kg
- Cement 300 kg
- Water 120l kg</p>
      <p>The relationship between water and cement a / c = w is of a
great importance.</p>
      <p>
        For a perfect reaction of cement, a ratio w equal to 0.28 [
        <xref ref-type="bibr" rid="ref9">9</xref>
        ]
which would be the reaction stoichiometric ratio would suffice.
In reality, this ratio is slightly increased to allow a better
hydration of cement and provide the mixture with certain
workability.
      </p>
      <p>Strength and permeability of concrete.</p>
      <p>During the testing phase of TAFIPACC processes
proposals to optimize the product output, both in terms of
physical characteristics and costs, will be defined.</p>
    </sec>
    <sec id="sec-6">
      <title>V. DETAILS OF THE PROCESS</title>
      <p>To test the TAFIPACC treatment, the evaluation, by means
of an appropriate analysis of the chemical - physical
characteristics of any potential sludge to be treated, has been
performed. The analysis allows both to choose the most
suitable sludge in terms of the content of pollutants, with which
to run tests, and to compare the chemical characteristics of the
pre- and post-treatment sludge.</p>
      <p>Tests have been carried out on the sludge falling within the
category "CER 19:08:13, sludges containing dangerous
substances coming from other treatments", i.e. sludge from
industrial wastewater (hazardous).</p>
      <p>The current methods for treating dangerous sludge are
illustrated below; and a possible scenario of application of the
method and its potential TAFIPACC benefit is simulated. The
selected waste can actually be decomposed into its two main
constituents:</p>
      <p>Residue or dried substance at 105°C% P 42.61</p>
    </sec>
    <sec id="sec-7">
      <title>Water</title>
      <p>%P
57.39</p>
      <p>The sludge then presents traces of hydrocarbons and heavy
metals. So 1000 kg of water results in about 570 kg of sludge.
In the inerting process by means of concrete packaging, the
water in the waste is used as the water to hydrate the cement.
The following ratios, which are necessary to obtain good
concrete, must have fixed values:</p>
      <p>- The water/cement ratio is kept low in order to ensure the
production of a concrete structure of high mechanical quality,
as it is crucial that the pollutants are blocked in the cement
matrix.</p>
      <p>
        - the ratio of the inert part with the cement that by a ratio of
the part of the hydraulic binder used and the solid inert part
from the sludge and by the granulometric Joint employed, must
be around 4 (+ Inert dry part of the sludge) = 3.85 (Cement)
- the ratio of lime and the solid matrix of the compound.
Lime is used to disinfect and eliminate the odorous part of the
waste. However, lime stabilization may allow odors to return;
To eliminate this problem and reduce pathogen levels, addition
of sufficient quantities of lime to raise and maintain the
biosolids pH [
        <xref ref-type="bibr" rid="ref10">10</xref>
        ] Its effectiveness is proportionate to the
quantity of lime used, relative to the entire solid matrix of the
compound consisting of the solid part of the sludge, aggregates
and concrete, resulting in a good value of about
0.17 (Lime) = 0.17 (+ Inert part dry sludge + cem.).
      </p>
      <p>When the present amount of dry sludge and water is
known, the amount of cement, lime and clean inert is obtained.</p>
      <p>Therefore the components needed to prepare concrete with
a ton of sludge are summarized below, stating the required
weight and volume.</p>
      <p>The numbers represent those which are necessary to pack
concrete using the input of a ton of sludge according to the
relations above. By converting the weight into volume, through
the specific weight, it appears that in order to carry out the
packaging of a ton of sludge a mixing tank of 3.78 mc is
necessary (in red in the table). The relationship introduced
above will be taken into account also in the preparation of a
new formula to be used downstream of a preliminary
dewatering of the sludge through the treatment using the new
TAFIPACC plant. The only ratio that will be altered is the one
between lime and the solid matrix of the compound. It will be
reduced, without altering the quality of mps in output, since
during the evaporation process inside the TAFIPACC
treatment plant the particles containing the volatile odoriferous
substances will also be removed.</p>
      <p>Drastically decreasing the presence of such substances
within the compound, it is also possible to reduce the amount
of lime required to eliminate odours. It is prudently estimated
that the intake of lime can be reduced by up to 20%, bringing
the ratio of 0.17 down to 0.137.</p>
      <p>If we aim to eliminate 15% by weight of the sludge in the
analysis, it can be done by extracting 1000kg from the initial
sludge and about 150lt of water incorporated therein prior to
the production of concrete. Considering the same sludge
without 150 kg of eliminated water, and keeping the
relationships stable and unvaried, less than that from lime (0.17
to 0.137), the new formula will be as follows, highlighting the
required values in green:
Lime
Concrete</p>
      <p>Below is a comparison between two treatment methods.
The delta value between the weights suggested by the two
formulas is highlighted.</p>
      <p>It can be stated that by using TAFIPACC treatment
method, the following savings of valuable materials can be
made, in terms of weight and price:
Total 86</p>
      <p>To treat then the same amount of sludge of 1000kg, a net
saving of 86 euros in terms of savings of valuable material
(aggregates, cement and lime) is obtained.</p>
    </sec>
    <sec id="sec-8">
      <title>VI. PROCESS ENERGY BALANCE</title>
    </sec>
    <sec id="sec-9">
      <title>Relative humidity RH (%)</title>
      <p>The amount of water vapour that can be contained in one
kg of dry air is not unlimited. Over a certain amount, the added
steam condenses in the form of minute droplets (i.e. fog effect).</p>
      <p>Relative humidity is the percentage of vapour contained in
the air in relation to the maximum quantity holding in it at a
certain temperature.</p>
      <p>For example: 1kg of air at a dry bulb temperature of 20 ° C
may at most contain 14.7g of water vapour (added steam
should condense); therefore, the mixture consisting of 1kg of
dry air and 14.7g of water vapour has, at a temperature of 20 °
C, the relative humidity equal to 100% (saturation conditions);
however, at the same temperature, if 1kg of dry air contained
7.35g of steam (i.e. half of the maximum amount of steam
miscible at 20°C), the mixture would be at a the relative
humidity of 50%.</p>
      <p>The relative air humidity is strictly related to the dry bulb
temperature.</p>
      <p>
        At parity of grams of water vapour present in a kg of dry
air, the relative humidity increases as the temperature
decreases; this can be explained as follows: the lower the air
temperature, the lower the miscibility of the water vapour in
the air [
        <xref ref-type="bibr" rid="ref11">11</xref>
        ].
      </p>
      <p>The psychometric chart at a given pressure (the one
reported herein at a pressure of 1,013 bar) represents curves of
various UR percentages. In particular, the upper one is the
curve of 100% RH that represents the dew point of water
vapour mixed in function of temperature and also indicates the
amount of water vapour miscible in 1 kg of air.</p>
      <p>Psychrometric chart</p>
      <p>By varying the conditions of the fluid, the water vapour
contained therein can then condense so that it is possible to pull
it out in the liquid form. Observing a simplified diagram, it can
be concluded that having a mass of air at 40 ° C at the relative
humidity equal to 100%, the total amount of water contained in
it results in almost 50 g / kg of air. Considering with a good
approximation that 1 kg of air corresponds to 1mc of air under
normal conditions, it can be stated that about 50 g / m3 of air
are inside.</p>
      <p>If the air is cooled to 5 ° C, the water content miscible in it
in the form of vapour passes from almost 50 g / kg to about 5 g
/ kg. As a result, 45 grams of water condense.</p>
      <p>Energy balance</p>
      <p>In order to estimate the energy contribution, the cycle
envisaged by TAFIPACC method is briefly summarized. The
method consists of a dehydration process of the sludge prior to
the concrete packaging. Considering the same 1000kg of
sludge and an elimination of water content equal to 15% by
sludge weight, the system must expel 150lt of water. This
process of water extraction from the sludge is completed in two
distinct phases that require a certain energy intake.</p>
      <p>In the first phase, it is necessary to evaporate water and the
volatile polluting substances in the sludge to separate them
from the sludgy mass and dissipate them in the air; whereas in
the second phase the dissipated vapours are captured by the
condensing coils.</p>
      <p>Considering the process in more detail, its phases are
indicated as follows:</p>
      <p>1) Heating of the sludge and the interior of the mixer up
to 40 °C.</p>
      <p>2) Evaporation of the liquid part from the sludge in
vapour state.</p>
      <p>3) Air Circulation charge of steam inside the
condensation circuit.</p>
      <p>4) Decresing the ambient temperature (vapour charge)
from 40 °C to 5 °C.</p>
      <p>5) Condensation of water</p>
      <p>For energy purposes, in steps 1) and 2) the energy to raise
the temperature and to enable further evaporation must be
produced. In point 3) energy is released to make the air
circulate. In steps 4) and 5) the same energy must be subtracted
from the current of air to decrease the temperature again and
cause the vapours to condense.</p>
      <p>To estimate the energy needed to carry out this cycle, the
Specific Heat (CS) of the compounds involved must be taken
into account:</p>
      <p>CS H2O(Liquid) = 4.180 [J/(kg °C)]
CS H2O(Steam) = 1.940 [J/(kg °C)]
CS Sludge (Dry part) = 1.000 [J/(kg °C)]</p>
      <p>CS Humid Air = 1.030 [J/(kg °C)]</p>
      <p>Specific heat indicates the energy required for the
temperature of a kg of compound to vary a degree. Latent heat
of vaporization (lv) indicates the energy required to make the
liquid evaporate.</p>
      <p>lv H2O</p>
      <p>= 2.272 [J/g]</p>
      <p>For purposes of energy calculation, it is assumed that for
simplicity only water evaporates and then condenses, for the
following reasons:</p>
      <p>1) water is by far the largest part of the volatile components
in sludge composition;</p>
      <p>2) the latent heat of evaporation and condensation of water
is among the highest. It is equivalent to 2272 (J / g), so,
evaporation of 1 gram of water requires 2272 joules of energy
(0.6311 watt-hours). Likewise, this energy must be subtracted
from 1 gram of water vapour to condense it.</p>
      <p>The energy needs are further examined point by point.
1) Increase in temperature from 15 ° C (average
temperature between summer and winter is considered) at 40 °
of 1000 kg of sludge consisting of 426kg of dry part and 574
kg of water.</p>
      <p>DT = 25 C
426 [kg] * 1.000 [J/(kg °C)] * 25 [°C] = 10.650 kJ  2.95
kWh
574 [kg] * 4.180 [J/(kg °C)] * 25 [°C] = 59.982kJ  16.6 kWh</p>
      <p>To heat the sludge from 15 to 40 °, 19:55 kWh are then
needed.</p>
      <p>2) Evaporation of 150kg (150.000g) of water to subtract
from the sludge, in order to get: 150,000 [g] * 2.272 [J / kg] =
340,800 kJ  94.6 kWh</p>
      <p>This energy will be administered to the sludge in two
forms:
 70 kWh heating resistors on the tank bottom
 45 kWh Mixing (Friction)</p>
      <p>The first cited energy will be delivered to the sludge in
drying by the resistances that are mounted under the tank
bottom. The second contribution will be provided by the
mixing engine. The mixer will have installed engine power
equal to 135kW.</p>
      <p>This engine power will be fully exploited when the mixer
works at full speed and full load. In the first phase of drying the
mixer will contain only 1000kg of sludge which must be
dehydrated. In this phase the mixing engines will exploit only a
portion of the energy consumable by them which can be
estimated at 30% of the nominal value corresponding to 45
kW.</p>
      <p>This power is used to stir the sludge in drying, and then the
friction of the material ultimately converts into thermal energy
and therefore heat. Clearly, this power will be required for the
longest duration of only one drying step.</p>
      <p>After completing the dehydration, the mixer will be loaded
with the other components to produce 2.8mc of concrete and
employ 135kW for mixing a couple of minutes. This amount of
energy is not considered because in any case there would be no
matter TAFIPACC treatment.</p>
      <p>3) To calculate the air inside the tank mixing with water
from the sludge one can refer to the following psychometric
chart (Fig. 3).</p>
      <p>The content of water miscible with the air at a temperature
of 40 ° C is almost 50 grams. Handing in the condensing coils
will bring the temperature to 5 °. At this temperature,
maintaining a relative humidity equal to 100%, the water
vapour contained in the miscible kg of processed air passes
from 50 to 5 grams. The water vapour-laden air after passing
through the condenser coil will have then downloaded 45
grams of water.</p>
      <p>A kg of air corresponds to approximately 1mc of air under
normal conditions. We know that for every cubic meter of air,
45 grams of water can be extracted; so, in order to extract 150lt
of water (150,000 grams) at least: 150,000 / 45 = 3333 cubic
meters of air will have to be processed.</p>
      <p>4) Taking the count on the basis of an hour and putting
some mc flow to make up for any losses, it will be necessary to
recirculate a fan at 4000mc / h flow rate. For a prevalence of
approximately 400mm of water column, an aspirator of this
kind will require a power of about 10kW.</p>
      <p>Reduction of temperature from 40 °C to 5 °C 150 kg of
water vapour in the air:</p>
      <p>DT = 35 °C
150 [kg] * 1.940 [J/(kg °C)] * 35 [°C] = 10.185 kJ  2.82
kWh</p>
      <p>To cool the water vapor from 40 °C to 15 °C, 2.82 kWh are
needed.</p>
      <p>1) Condensation of 150kg (150.000g) of water to be
subtracted from the sludge, so to get:
150.000 [g] * 2.272 [J/kg] = 340.800 kJ  94.6 kWh
Once diffused water in the form of steam flows through the
condenser batteries, 150lt of water are needed to condense
again by using additional 92 kWh. The latent heat of
condensation is in fact similar to that of evaporation.</p>
      <p>The condensing coils will have an installed capacity of
95kW to condense the amount of 150 kg water vapour.</p>
      <p>For simplicity of calculation the duration of the drying
process equivalent to 1 hour is assumed, where the fan
consumes 10kWh.</p>
      <p>The following approximations are calculated by excess:</p>
    </sec>
    <sec id="sec-10">
      <title>1) Heating Sludge</title>
      <p>2) Evaporation
3) Air-handling
4) Steam cooling
5) Condensation
Total
20kW
95KWh
10kWh
5kWh
95KWh
225KWh</p>
      <p>This allows calculating the required energy and power, so,
in order to extract 150lt of water from the sludge, for the
treatment of 1000kg of sludge, 225kWh are necessary.</p>
      <p>It is emphasized that the above calculations have been
carried out without considering the recovery of heat that could
be implemented in the radiators, and are therefore certainly
estimated above.</p>
      <p>Economic analysis</p>
      <p>Considering the price of electricity of 0.16 euros / kWh, the
total costs will be 0.16 € / kWh x225 kWh = € 36 for the
treatment of 1 ton of dangerous sludge.</p>
      <p>Drawing up a balance between the precious raw material
savings (as seen in the previous paragraph, and amounted to €
86) and the expenditure of additional energy, by using the
proposed TAPIFACC treatment plant, the net cost savings for
the dangerous sludge treatment of 1000kg will be:</p>
      <p>COST SAVINGS = 86-36 = 50 Euro / Ton of Sludge
Below is shown the comparison of two different recipes
usable with traditional system and system with TAFIPACC
dehydration.</p>
      <p>Furthermore, other important economic considerations can
be discussed.</p>
      <p>The table below compares two different treatment methods,
i.e. the traditional system and TAFIPACC dehydration in terms
of the composition of 1 cubic meter of concrete as a product of
the two different methods:</p>
      <p>Using TAPIFACC method, a cubic meter of concrete is
produced with a greater amount of dry sludge (154 kg vs. 112
kg) and fewer raw materials (lime, 257 kg vs. 317 kg).</p>
      <p>From the economic viewpoint, the cost of waste
contribution to the reception facilities would amount to 174
Euros per ton (see Annex to this report via email and the
"anac" tender awarded € 1,081,700 to treat 5 800 tons of
sludge).</p>
      <p>Considered that the transport incidence is 12.5 € / t, the
treatment costs per ton of sludge results in 1 081 700/5800 =
186.5 € / t; minus the shipping costs 1865.5-12.5 = 174 € / t, so
- Production: 3.78 cubic meters of concrete per ton of
treated sludge
- Revenue from sale = 35 x 3.78 = 132.3 €
- Cost of raw material production (considering the negative
supply of sludge) = 80.40 € per ton of treated sludge.</p>
      <p>With the method TAFIPACC:
-Production: 2.75 cubic meters of concrete per ton of
treated sludge
- Revenue from sale = 35 x 2.75 = 97.3 €
- Cost of raw material production (considering negative
sludge supply) = 5.60 € per ton of treated sludge (i.e. spending
less on raw materials than paying for the transfer of sludge)
- Energy costs (more than the traditional process) = 36 €
per ton of treated sludge (see previous paragraphs).</p>
      <p>TOTAL COST TO TREAT A TON OF SLUDGE WITH</p>
      <p>Therefore making an economic comparison between the
two treatments for 1 ton of sludge, the following conclusions
can be drawn:</p>
      <p>Employing the TAFIPACC method, an additional gain of
14.6 € per ton of treated sludge equals about 30% margin more
than the current (14.6 / 52.3) is derived.
the price for the treatment of 1 ton of sludge is 174 € / t).
Considering the costs of valuable materials outlined in the table
above, and learning that the selling price of 1 cubic meter
concrete is 35 €, the treatment of 1 ton of sludge amounts to:
With TRADITIONAL method:</p>
      <p>TOTAL COST TO TREAT A TON OF SLUDGE WITH</p>
      <p>Besides the economic advantage outlined above, there are
other benefits which are difficult to quantify economically:
• 30% less production of blocks (2.7 compared to 3.7 cubic
metres per 1 ton of sludge):
• Less handling within the plant;
• Less area for storage;
• More ease of sale (it must sell less);
• Minor volume needed to mix 1 ton of sludge (3.78 to 2.7
cubic meters);</p>
      <p>• Smaller mixing bath (only 3mc,. mixers 2 mc, where 2
cycles are needed to treat 1 ton of sludge, and a mixer of 4 mc
does not exist on the market)</p>
      <p>• Fewer raw materials employed, less amount of storage
needed;
• Greater ability to increase the amount sludge to be treated.</p>
      <p>Considering the amount of sludge transferred in the last two
years to the 4R, which is approximately 10 000 t, and
supposing that it had been treated by using the TAFIPACC
method, it would have resulted in a profit of 14.6 € / t x 10 000
t = 146 000 € over the last two years.</p>
      <p>In recent years the 4R has limited the amount of sludge to
be treated but in the coming years, thanks to the convenience of
the TAFIPACC system, it will be able to treat about 30,000
tons of sludge.</p>
      <p>With this amount of sludge the annual revenue would
amount to around € 440 000.</p>
      <p>Assuming the sale price at 4R (see paragraph 11 of this
report) amounting to 80,000 €, the required amount of sludge
to be treated in order to pay back the cost of the plant is about
5,600 t of sludge. Considering the current data on 4R sludge
processing amounts one year will be enough.</p>
    </sec>
    <sec id="sec-11">
      <title>VII. SCALED PROTOTYPE TESTING</title>
      <p>Before launching the design, modeling and implementation
of the TAFIPACC project prototype, a small prototype on a
reduced scale was developed, in order to test the equipment
and conduct tests on small amounts of sludge to find the right
components to add in the mixing stage for waste recovery.
Analyzing dozens of samples obtained during the tests with the
scaled prototype of the TAFIPACC system, it was possible to
identify a modus operandi that would permit optimization of
the process in terms of energy and time.</p>
      <p>Fig. 7. Scaled prototype.</p>
      <p>After hundreds of tests with scale prototype the following
conclusions can be drawn:
- The reducing process of the sludge weight improves if
inert is also included in the process of mixing;</p>
      <p>- The times of the sludge weight reduction decrease
substantially with the addition of insulation in the tank mixing;
- The times of the sludge weight reduction diminish
significantly with the increase of the temperature at which the
mixing process and then the heating of the mixing tank take
place.</p>
    </sec>
    <sec id="sec-12">
      <title>CONCLUSIONS</title>
      <p>In comparison to the currently available industrial sludge
treatment methods, the proposed method intends to
significantly reduce the mobility of contaminants contained in
the sludge. The developed method allows extracting the
volatile portion of the sludge by means of a heating device
applied for the first time to a concrete mixer of great
dimensions and thus resulting in lower environmental impact.
This promotes a desired increase of temperature so as to trigger
evaporation of volatile substances and enable their separation
from sludge. The mixer, flanked by an air recirculation circuit,
is also equipped with a moisture detection probe. An added
value of a sludge treatment process is determined with the
profitable reuse of the output material. To treat 3 tons of
sludge, 4.7 tons of clean inert and 0.6 tons of cement were
used. During the TAFIPACC process testing, the best solution
to optimize the output was defined, both in terms of physical
characteristics and costs incurred. In particular, tests and
optimizations were performed using hazardous sludge "CER
19:08:13 sludges containing dangerous substances from other
treatments", i.e. sludge from industrial wastewater (hazardous).
By using the TAFIPACC method, in which the amount of
dangerous substances inside the compound is dramatically
decreased, it is also possible to reduce the amount of lime
required to eliminate odors. It was estimated that it is possible
to reduce the amount of lime by up to 20%, bringing the ratio
of 0.17 down to 0.137. The research was concerned with the
development of virtual models and relative analytic
calculations, as well as the performance of experimental
measurements in the field in order to optimize every single
component to come up with innovative design. In particular,
the research involved static and dynamic simulations, structural
dimensioning and prototype creation of the main components
of the plant using 3D printing technology on 1:10 scale.</p>
    </sec>
  </body>
  <back>
    <ref-list>
      <ref id="ref1">
        <mixed-citation>
          [1]
          <string-name>
            <surname>Gupta</surname>
            ,
            <given-names>V. K.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Ali</surname>
            ,
            <given-names>I.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Saleh</surname>
            ,
            <given-names>T. A.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Nayak</surname>
            ,
            <given-names>A.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Agarwal</surname>
            ,
            <given-names>S.</given-names>
          </string-name>
          (
          <year>2012</year>
          ).
          <article-title>Chemical treatment technologies for waste-water recycling-an overview</article-title>
          .
          <source>Rsc Advances</source>
          ,
          <volume>2</volume>
          (
          <issue>16</issue>
          ), (pp.
          <fpage>6380</fpage>
          -
          <lpage>6388</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref2">
        <mixed-citation>
          [2]
          <string-name>
            <surname>Deligiannis</surname>
            ,
            <given-names>V</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Manesis</surname>
            ,
            <given-names>S.</given-names>
          </string-name>
          (
          <year>2008</year>
          ).
          <article-title>Concrete batching and mixing plants: A new modeling and control approach based on global automata</article-title>
          .
          <source>Automation in Construction</source>
          ,
          <volume>17</volume>
          (
          <issue>4</issue>
          ),
          <fpage>368</fpage>
          -
          <lpage>376</lpage>
          .
        </mixed-citation>
      </ref>
      <ref id="ref3">
        <mixed-citation>
          [3]
          <string-name>
            <surname>Ambu</surname>
            ,
            <given-names>R.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Bertetto</surname>
            ,
            <given-names>A. M.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Mazza</surname>
            ,
            <given-names>L.</given-names>
          </string-name>
          (
          <year>2016</year>
          ).
          <article-title>Re-design of a guide bearing for pneumatic actuators and life tests comparison</article-title>
          .
          <source>Tribology International</source>
          ,
          <volume>96</volume>
          ,(pp.
          <fpage>317</fpage>
          -
          <lpage>325</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref4">
        <mixed-citation>
          [4]
          <string-name>
            <surname>Gamez-Montero</surname>
            ,
            <given-names>P. J.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Salazar</surname>
            ,
            <given-names>E.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Castilla</surname>
            ,
            <given-names>R.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Freire</surname>
            ,
            <given-names>J.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Khamashta</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Codina</surname>
            ,
            <given-names>E.</given-names>
          </string-name>
          (
          <year>2009</year>
          ).
          <article-title>Misalignment effects on the load capacity of a hydraulic cylinder</article-title>
          .
          <source>International Journal of Mechanical Sciences</source>
          ,
          <volume>51</volume>
          (
          <issue>2</issue>
          ),
          <fpage>105</fpage>
          -
          <lpage>113</lpage>
          .
        </mixed-citation>
      </ref>
      <ref id="ref5">
        <mixed-citation>
          [5]
          <string-name>
            <surname>Calì</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Oliveri</surname>
            ,
            <given-names>S. M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Sequenzia</surname>
            ,
            <given-names>R.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Fatuzzo</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          (
          <year>2017</year>
          ).
          <article-title>An effective model for the sliding contact forces in a multibody environment</article-title>
          .
          <source>In Advances on Mechanics, Design Engineering and Manufacturin</source>
          (pp.
          <fpage>675</fpage>
          -
          <lpage>685</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref6">
        <mixed-citation>
          [6]
          <string-name>
            <surname>Calì</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Oliveri</surname>
            ,
            <given-names>S. M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Ambu</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Fichera</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          (
          <year>2018</year>
          ).
          <article-title>An integrated approach to characterize the dynamic behaviour of a mechanical chain tensioner by functional tolerancing</article-title>
          .
          <source>Strojniski Vestnik/Journal of Mechanical Engineering</source>
          ,
          <volume>64</volume>
          (pp.
          <fpage>245</fpage>
          -
          <lpage>257</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref7">
        <mixed-citation>
          [7]
          <string-name>
            <surname>Ambu</surname>
            ,
            <given-names>R.</given-names>
          </string-name>
          (
          <year>2013</year>
          ).
          <article-title>A method with a statistical approach for the evaluation of tolerance chains</article-title>
          .
          <source>In Advanced Materials Research</source>
          <volume>651</volume>
          , (pp.
          <fpage>601</fpage>
          -
          <lpage>606</lpage>
          ).
          <source>Trans Tech Publications.</source>
        </mixed-citation>
      </ref>
      <ref id="ref8">
        <mixed-citation>
          [8]
          <string-name>
            <surname>Frigione</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          (
          <year>2010</year>
          ).
          <article-title>Recycling of PET bottles as fine aggregate in concrete</article-title>
          .
          <source>Waste management</source>
          ,
          <volume>30</volume>
          (
          <issue>6</issue>
          ), (pp.
          <fpage>1101</fpage>
          -
          <lpage>1106</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref9">
        <mixed-citation>
          [9]
          <string-name>
            <given-names>ACI</given-names>
            <surname>Committee</surname>
          </string-name>
          , American Concrete Institute, &amp; International Organization for Standardization. (
          <year>2008</year>
          ).
          <article-title>Building code requirements for structural concrete (ACI 318-08) and commentary</article-title>
          . American Concrete Institute.
        </mixed-citation>
      </ref>
      <ref id="ref10">
        <mixed-citation>
          [10]
          <string-name>
            <surname>Williford</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Chen</surname>
          </string-name>
          , W. Y.,
          <string-name>
            <surname>Shamas</surname>
            ,
            <given-names>N. K.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Wang</surname>
            ,
            <given-names>L. K.</given-names>
          </string-name>
          (
          <year>2007</year>
          ).
          <article-title>Lime stabilization</article-title>
          .
          <source>In Biosolids Treatment Processes</source>
          (pp.
          <fpage>207</fpage>
          -
          <lpage>241</lpage>
          ). Humana Press.
        </mixed-citation>
      </ref>
      <ref id="ref11">
        <mixed-citation>
          [11]
          <string-name>
            <surname>Yadav</surname>
            ,
            <given-names>Y. K.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Kaushik</surname>
            ,
            <given-names>S. C.</given-names>
          </string-name>
          (
          <year>1991</year>
          ).
          <article-title>Psychometric technoeconomic assessment and parametric studies of vapor-compression and solid/liquid desiccant hybrid solar space conditioning systems</article-title>
          .
          <source>Heat Recovery Systems and CHP</source>
          ,
          <volume>11</volume>
          (
          <issue>6</issue>
          ), (pp.
          <fpage>563</fpage>
          -
          <lpage>572</lpage>
          ).
        </mixed-citation>
      </ref>
      <ref id="ref12">
        <mixed-citation>
          [12]
          <string-name>
            <surname>Kapuściński</surname>
            ,
            <given-names>T.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Nowicki</surname>
            ,
            <given-names>R.K.</given-names>
          </string-name>
          and
          <string-name>
            <surname>Napoli</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          ,
          <year>2017</year>
          , June.
          <article-title>Comparison of Effectiveness of Multi-objective Genetic Algorithms in Optimization of Invertible S-Boxes</article-title>
          .
          <source>In International Conference on Artificial Intelligence and Soft Computing</source>
          (pp.
          <fpage>466</fpage>
          -
          <lpage>476</lpage>
          ). Springer.
        </mixed-citation>
      </ref>
      <ref id="ref13">
        <mixed-citation>
          [13]
          <string-name>
            <surname>Woźniak</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Połap</surname>
            ,
            <given-names>D.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Napoli</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          and
          <string-name>
            <surname>Tramontana</surname>
            ,
            <given-names>E.</given-names>
          </string-name>
          ,
          <year>2017</year>
          .
          <article-title>Application of bio-inspired methods in distributed gaming systems</article-title>
          .
          <source>Information Technology And Control</source>
          ,
          <volume>46</volume>
          (
          <issue>1</issue>
          ), pp.
          <fpage>150</fpage>
          -
          <lpage>164</lpage>
          .
        </mixed-citation>
      </ref>
      <ref id="ref14">
        <mixed-citation>
          [14]
          <string-name>
            <surname>Bonanno</surname>
            ,
            <given-names>F.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Capizzi</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Sciuto</surname>
            ,
            <given-names>G.L.</given-names>
          </string-name>
          and
          <string-name>
            <surname>Napoli</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          ,
          <year>2015</year>
          ,
          <string-name>
            <surname>June.</surname>
          </string-name>
          <article-title>Wavelet recurrent neural network with semi-parametric input data preprocessing for micro-wind power forecasting in integrated generation Systems</article-title>
          .
          <source>In International Conference on Clean Electrical Power (ICCEP)</source>
          , (pp.
          <fpage>602</fpage>
          -
          <lpage>609</lpage>
          ). IEEE.
        </mixed-citation>
      </ref>
      <ref id="ref15">
        <mixed-citation>
          [15]
          <string-name>
            <surname>Capizzi</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Sciuto</surname>
            ,
            <given-names>G.L.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Monforte</surname>
            ,
            <given-names>P.</given-names>
          </string-name>
          and
          <string-name>
            <surname>Napoli</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          ,
          <year>2015</year>
          .
          <article-title>Cascade feed forward neural network-based model for air pollutants evaluation of single monitoring stations in urban areas</article-title>
          .
          <source>International Journal of Electronics and Telecommunications</source>
          ,
          <volume>61</volume>
          (
          <issue>4</issue>
          ), pp.
          <fpage>327</fpage>
          -
          <lpage>332</lpage>
          .
        </mixed-citation>
      </ref>
      <ref id="ref16">
        <mixed-citation>
          [16]
          <string-name>
            <surname>Zanetti</surname>
            ,
            <given-names>E. M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Aldieri</surname>
            ,
            <given-names>A.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Terzini</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Calì</surname>
            ,
            <given-names>M.</given-names>
          </string-name>
          ,
          <string-name>
            <surname>Franceschini</surname>
            ,
            <given-names>G.</given-names>
          </string-name>
          , &amp;
          <string-name>
            <surname>Bignardi</surname>
            ,
            <given-names>C.</given-names>
          </string-name>
          (
          <year>2017</year>
          ).
          <article-title>Additively manufactured custom load-bearing implantable devices: grounds for caution</article-title>
          .
          <source>Australasian Medical Journal</source>
          ,
          <volume>10</volume>
          (
          <issue>8</issue>
          ), p.
          <fpage>694</fpage>
          .
        </mixed-citation>
      </ref>
    </ref-list>
  </back>
</article>